nano-silica phosphoric acid: an efficient catalyst for one-pot synthesis of 3,4-dihydropyrimidin-2(1h)-ones (thiones) under solvent-free or sonication conditions

نویسندگان

abdolhamid bamoniri

bi bi fatemeh mirjalili

sedigheh nazemian

چکیده

two simple protocols for the synthesis of three-component condensation reaction of an aldehyde, β-ketoester and urea or thiourea to obtain the 3, 4-dihydropyrimidin-2(1h)-ones (thiones) using nano silica phosphoric acid are reported. short reaction times, high yields, reusability of catalyst and easy workup are some advantages of these protocols.

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منابع مشابه

Nano-Silica phosphoric acid: an efficient catalyst for one-pot synthesis of 3,4-dihydropyrimidin-2(1H)-ones (thiones) under solvent-free or sonication conditions

Two simple protocols for the synthesis of three-component condensation reaction of an aldehyde, β-ketoester and urea or thiourea to obtain the 3, 4-dihydropyrimidin-2(1H)-ones (thiones) using nano silica phosphoric acid are reported. Short reaction times, high yields, reusability of catalyst and easy workup are some advantages of these protocols.

متن کامل

Nano-Silica phosphoric acid: an efficient catalyst for one-pot synthesis of 3,4-dihydropyrimidin-2(1H)-ones (thiones) under solvent-free or sonication conditions

Two simple protocols for the synthesis of three-component condensation reaction of an aldehyde, β-ketoester and urea or thiourea to obtain the 3, 4-dihydropyrimidin-2(1H)-ones (thiones) using nano silica phosphoric acid are reported. Short reaction times, high yields, reusability of catalyst and easy workup are some advantages of these protocols.

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Nano-Silica Phosphoric Acid: An Efficient Catalyst for One-Pot Synthesis of Tetrahydrobenzo[a]xanthenes-11-one Under Solvent- Free or Sonication Conditions

Two simple protocols for the synthesis of tetrahydrobenzo[a]xanthenes-11-ones using nano silica phosphoric acid are reported. Short reaction times, high yields, reusability of catalyst and easy workup are some advantages of these protocols.

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nano-silica phosphoric acid: an efficient catalyst for one-pot synthesis of tetrahydrobenzo[a]xanthenes-11-one under solvent- free or sonication conditions

two simple protocols for the synthesis of tetrahydrobenzo[a]xanthenes-11-ones using nano silica phosphoric acid are reported. short reaction times, high yields, reusability of catalyst and easy workup are some advantages of these protocols.

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4-Sulfobenzoic Acid as an Efficient Catalyst for the Preparation of 3,4-dihydropyrimidin-2-(1H)-ones Under Solvent-free Conditions

In this research, one-pot three-component synthesis of 3,4-dihydropyrimidin-2-(1H)-ones havebeen developed using Biginelli reaction from the interaction between ethyl/methyl acetoacetate,aromatic aldehydes, and urea/thiourea in the presence of 4-sulfobenzoic acid as a new, effective,inexpensive, and available bronsted acid. Avoidance of toxic and dangerous solvents, easy isola...

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Nano Silica Phosphoric Acid: An Efficient Catalyst for the One- Pot Synthesis of 1, 2, 4, 5-Tetrasubstituted Imidazoles

Two  simple  protocols  for  the  synthesis  of  1,  2,  4,  5-   tetrasubstitutedimidazoles  using  nano-SPA  as  a  reusable,  eco-   friendly,  inexpensive,  and  efficient  catalyst  are  reported.  Short   reaction  times,  high  yields,  scale-up  and  easy  workup  are  the   advantages of these protocols.

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عنوان ژورنال:
iranian journal of catalysis

ناشر: islamic azad university, shahreza branch

ISSN 2252-0236

دوره 2

شماره 1 2012

کلمات کلیدی
[ ' b i g i n e l l i r e a c t i o n ' , 3 , 4 , ' d i h y d r o p y r i m i d i n ' , ' 2 ( 1 h ) ' , ' o n e s ' , 4 , ' d i h y d r o p y r i m i d i n ' , ' 2 ( 1 h ) ' , ' t h i o n e s ' , ' h e t e r o g e n e o u s c a t a l y s t ' , ' m u l t i ' , ' c o m p o n e n t r e a c t i o n s ' , ' n a n o s i l i c a p h o s p h o r i c a c i d ' , ' s o n i c a t i o n c o n d i t i o n ' ]

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